Bis[4-amino-3,5-bis(pyridin-2-yl)-4H-1,2,4-triazole-κ2N2,N3]bis(benzene-1,2-dicarboxylic acid-κO)copper(II) bis(2-carboxybenzoate)

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4-[(2-Bromo­benzyl­idene)amino]-3-(pyridin-4-yl)-1H-1,2,4-triazole-5(4H)-thione

In the title compound, C(14)H(10)BrN(5)S, the dihedral angle between the triazole ring and the pyridine and bromo-benzene rings are 26.42 (13) and 6.28 (13)°, respectively. The molecule exists as a thione in the solid state. In the crystal, mol-ecules are linked by N-H⋯N hydrogen bonds, generating [010] C(8) chains.

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4-Amino-3,5-di-2-pyridyl-4H-1,2,4-triazole

In the crystal structure of the title compound, C(12)H(10)N(6), the mol-ecules deviate slightly from planarity. The plane of the central triazole ring makes angles of 6.13 (9) and 3.28 (10)° with the pyridyl ring planes. Intra-molecular N-H⋯N inter-actions form six-membered closed rings. The crystal packing also shows weak C-H⋯π and C-H⋯N inter-actions.

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4-Amino-3,5-dimethyl-4H-1,2,4-triazole

In the title compound, C(4)H(8)N(4), inter-molecular N-H⋯N hydrogen bonds involving the amino groups and triazole N atoms form a two-dimensional sheet.

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Synthesis of thiadiazoles and 1,2,4-triazoles derived from cyclopropane dicarboxylic acid.

New heterocyclic derivatives of cyclopropane dicarboxylic acid comprising thiadiazole and 1,2,4-triazole moieties are reported. Reaction of 1,1-cyclopropane dicarboxylic acid (1) with thiosemicarbazide and phosphorous oxychloride resulted in 1,1-bis (2-amino-1,3,4-thiadiazol-5- yl)cyclopropane (2). Cyclopropane dicarboxylic acid thiosemicarbazide (6) was converted into 1,1-bis(3-thio-4H-1,2,4-t...

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3-(Adamantan-1-yl)-4-(prop-2-en-1-yl)-1H-1,2,4-triazole-5(4H)-thione

The title mol-ecule, C(15)H(21)N(3)S, exists as the thione tautomer in the solid state. The 1,2,4-triazole ring is almost planar (r.m.s. deviation = 0.004 Å) and the prop-2-en-1-yl chain is close to being perpendicular to this plane [C-N-C-C torsion angle = 77.1 (5)°]. In the crystal, centrosymmetric dimeric aggregates are formed by pairs of N-H⋯S hydrogen bonds as parts of eight-membered (⋯HNC...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812000128